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DAVID  PUBLISHING
D
Process and Extraction of Natural Fibers in the Artistic Application
Maria Gabriela Punín Burneo
Universidad Tecnica Particular de Loja, Ecuador

Received: March 11, 2011 / Accepted: April 07, 2011 / Published: February 10, 2012.

Abstract:This research discusses the basic processes of extraction and handling of fibers used in the production of the natural fiber paper. Dyes are based on natural colorings derived from native plants such as avocado, walnut, suckling pig which are traditional techniques of the ethnic Shuar group of the province of Zamora Chinchipe.The study of natural fibers for paper developed as an alternative artform, a compliment to photography, sculpture and handcrafts and helps us identify the contributions that nature gives us in the formation of work of art. The varieties of texture, color, and transparency are also means for creativity.

Key words:Natural fibers, arts, crafts, Raquis spine.


1. Introduction
Nowadays the development of environmentally friendly products is at its peak, due to the constant search for practical solutions to environmental problems and the urgent need to shift from non-renewable products. Multiple investigations have been developed in recent decades trying to find new materials in order to replace the conventional ones.
Products thatdue to its long degradation process, have been accumulated forming huge piles of rubbish.[1] A novel alternative is the use of renewable raw materials like natural fibers such assisal and banana, previously treatedwith sodium hydroxideto removeitslignin, thus it helps to increase its resistance.[2]On the other handan alternativeto replace thesodiumhydroxide(caustic soda) may be the rotorfermentation of thenatural fiber.[3]
Due to the highdemand in theuse ofcraftsand art and to providealternatives usingenvironmentally friendly materials, many investigations have beendeveloped based onthis alarmingnews, developingnewmethods in order to create productsthat do not createenvironmental harm.[4]
This studyaims to investigatethe utilities thatcan be givento natural fibersbecause inmany cases it passesunnoticed andit can be found innature, an interesting fact about it is thatit does not harmthe environment
2. Method
Natural fiber paper is handmade, in which industrial machinery is not used, using plants from our provinces and in some cases using raw materials considered waste in our environment.
Raw materials for the paper were selected in order to then proceed with their collection and extraction. Options included:varying fiber length, libebananas fibers, vascular or seeds, fresh plants, dried plant parts, pod remains, coconut crusts, or stalks.[4]
Another resource was the use of wild plants found by the road. In this research plants from the province of Loja were analyzed in order to ascertain which of them contained a major quantity of fiber, as can be seen in table one.




WOODY FIBROTIC PLANTS OF THE PROVINCE OF LOJA
Common name
Scientific Name
Habit
Pita
American Agave L
Herb
Agave
Agave angustifolia Haw.
Herb
Sisal
Agave sisalana Perrine
Herb
Pita Fiber
FurcraeaandinaTrel.
Bush
Yucca
Yucca  aloifolia L
Bush
Coconut palm
Coconuts nucifera L
tree
Kentia Palm
HoweaforsterianaBecc
Herb
Date Palm
Phoenix dactylifera L.
tree
Palmitoelevado
Trachycarpusfortunei (Hook) H. Wendl
tree
Washingtonia
Washingtoniafilifera H. Wendl
tree
Pineapple
Annanascomosus (L.) Merr.
Herb
Reed mace
Schoenoplectuscalifornicus (CA. Mey.) Soyák
Herb
Broom
Spartiumjunceum L.
Bush
Inseed
Linunusitatissimum  L.
Herb
Flor de rey
Hibiscus rosa-sinensis L.
Herb
Malva de florchica
Mallow parviflora L
Herb
Sanalotodo
Sidacordifolia L.
Herb
Pichana
Sidarhombifolia  L
Subshrub
Cosacosilla
Urenalobata L
Herb
Banana tree
Musa xparadisiaca L.
tree
Castillitos
AgrostisalpinaScop
Herb
Andropogon
AndropogonaequatoriensisHitchc.
Herb
Lemon verbena
Andropogoncitratus (DC) Stapf
Herb
Cariamanga
AndropogongayanusKunth
Herb
Gramadulce
Anthoxanthumodoratum L.
Herb
Grama de color
Antoxanthumalpinun Love et Love
Herb
Fodder
AristidaecuadoriensisHenrard
Herb
Tresbarbas
Aristidaadscensionis L.
Herb
Giant reed
Arundodonax L.
Herb
Chigua
Aulonemiahaenkei (Rupr.) McClure
Herb
Oats
Satif oat L.
Herb
Avenula
Avenulapraeusta (Rchb) Holub
Herb
Couch-grass
Axonopuselegantulus (J. Presl) Hitchc.
Herb
Micay
AxonopusmicayGarcía-Barr.
Herb
Pato Imperial
Axonopusscoparius (Fluggé) Kuhlm.
Herb
Bamboo
BambusavulgarisSchrad. ex J.C. Wendl.
tree
Barboncillo
Bothriochloaischaemon (L) Keng
Herb
Hurricane Herb
Bothriochloaischaemon (L) Keng
Herb
Laston
Brachypodiumpinnatum (L) Beauv.
Herb
Tembladera
Briza media L.
Herb
Cebadilla
Bromus erectus Hudson
Herb
Crespìllo
Calamagrostispseudophragmites (Haller) Koeler
Herb
Trilla
Chrysopogongryllus (L). Trin
Herb
Quila
ChusqueascandensKunth
Herb
Cortadera
Cortaderiasericantha (Steud.) Hitchc.
Herb
                 
WOODY FIBROTIC PLANTS OF THE PROVINCE OF LOJA
Common name
Common name
Common name
Gramón
Cynodondactylon (L.) Pers.
Herb
Dactilo
Dactylisglomerata L.
Herb
Pangola
DigitariadecumbensStent
Herb
Cañuela de los prados
FestucacircummediterraneaPatzke
Herb
Guadua
GuaduaangustifoliaKunth
Herb
Pindo
Gyneriumsagittatum (Aubl.) P. Beauv.
Herb
Sweet pasture
Hierochloeodorata (L) Wahlenb
Herb
Woolly pasture
Holcusmollis L
Herb
Barley
Hordeumvulgare  L.
Herb
Raigras annual
Loliummultiflorum Lam.
Herb
Avenaloca
Melicaciliata L
Herb
Yagua
Olyralatifolia L.
Herb
Rice
Oriza sativa L.
Herb
Yaguà
Orthocladalaxa (Rich.) P. Beauv.
Herb
Pasture of the partridge
Panicumcapillare L,
Herb
Klein
Panicummiliaceum L.
Herb
Guinea
Panicumrepens L.
Herb
Chépica
Paspalumdistichum L.
Herb
Kikuyo
Pennisetumclandestinun L
Herb
Elephant
PennisetumpurpureumSchumach
Herb
Fountain Herb
Pennisetumsetaceum (Forsskal) Chiov
Herb
Espiguilla
Poaannua L
Herb
Pilosa
PoainfirmaKunth
Herb
Ear
Poatrivialis L
Herb
Reed
Saccharumofficinarum L
Herb
Lagartera
Setariaverticillata  (L) Beauv
Herb
Almorejo
Setariaviridis (L) Beauv
Herb
Sorghum
Sorghum halepense (L.) Pers.
Herb
Estipa
StipacapensisThunb
Herb
Esparto
Stipatenacissima  L
Herb
Wheat
Triticumsativum Lam.
Herb
Maize
Zeamays L
Herb
Ortiga
BoehmeriaramifloraJacq.
bush
Nettle
Urticabianorii (Knoche) Paira
Herb
Roman Nettle
Urticapilulifera L.
Herb


One example of the process is banana tree rachis which is triturated in a roller mill, thereby eliminating enzymatic liquids, water, organic acids and other elements of low molecular weight called extractives.
The plant is 'cooked' by chemical extraction using an alkali solution, sodium hydroxide (caustic soda) in an amount proportionate to the fiber that is cooked.[5] In this process the walls of the fibers swell and become more absorbent. The fibers soften thereby removing fats and other elements [6].Some fibers are harder than others, such as cotton and abaca[7].The planted were tested at 30, 45, 60 and 120 min of cooking.
After cooking the fibers need to be rinsed thoroughly to leave no traces of alkali. The fibers are dried in
Fig.1Raquis spine.

Fig.2Raquis after trituration and from  elimination of enzymatic liquids.

sunlight at a temperature of about 26.6 °C, or alternatively in hot chambers to speed up the process. Then they are ready to be processed into pulp and be made into paper.
The best results obtained in the chemical extraction process were with the banana fiber (rachis), both from the standpoint of residual lignin and resistance to the heat, corresponding to 15% NaOH in 100 min cooking. [18]
As shorter fibers are tighter and create a more uniform sheet formation, it was necessary to also take into account fiber length. [22]
To form paper, a mucilage of Tuna,Nopal (Opuntiaficus) was used. This pulp also helps to drain water and obtain a consistent pulp[8]. After this operation is finished, a high viscosity fluid is obtained and can be used as a flocculant for the preparation of pulp. [1]  That is to say, the fluid allows the fiber to float in water and acts as a fiber dispersant delaying drainage of water in the formation of sheet [9].
A small amount of CMC (Carboxy Methyl Cellulose) is placed into a coating glaze. We had exerience with potato starch, corn, rice and native plants such as Mirabilis jalapa the same one which tuber contains starch. The fiber is not penetrated by the coating glaze. [24] The glaze covers the fibres protecting them from oxidation, which creates decomposition [10]. CMC is also used as an adhesive whichcan be added to the pulp vat prior to the leaf formation, where it is well-mixed. [12] Alternatively a coating glaze can be added to the dry leaf for humid artistic techniques as: watercolor, gouache. This coating glaze also works very well for procedures such as photography [11].
Leaf formation is made by hand. The amount of pulp put in the strainer varies depending on the desired thickness of the paper and the artistic aims. The paper takes shape when the atom’s fibers are joined to water molecules [12]. When these are flopped onto a plastic mesh frame to drain its molecules pullthe fibers with such strength that they get mixed among themselves and create new bonds, thereby



Fig.3 TunaNopal (Opuntiaficus) The "tuna" tree in the very moment the coagulant substance (mucilage) is poured out.

Fig.4 Leaf formation in the pulp state over a plastic mesh.


creating a solid surface.[13] y[14]
The drying of the leaf depends of the desired texture, as well as the artistic variations of color and transparency[15], which are important for handicrafts such as lamps, which emit light need to be an attractive, unique final product. [10]
When the leaf is completely dried, it is removed from the pellon and is ready for the finishing process. For the finishing touches the leaf is first smoothed on both sides with a rolling pin or electric iron. [21]  In this case a press has been used for the purposes of eliminating the air between fibers. Pressing also accelerates the leaf dehydration process (so the drying period is shorter than if one were to pull the paper over sackcloth directly after shaping it into the mold). At this stage of the process, seeds, threads, vegetable bark and fibers can be adhered to the leaf in order to give a truly handmade look. [9]
During this research we also explored the factors involving the addition of color to the paper. Experimentation with artificial dyes revealed that though the pigment adhered well to the fiber, the fiber did become weak and started losing resistance. The acquisition of dyes and synthetic colors also means the use of traditional local plant-based color pigments are being lost and this knowledge is need of rescue.[6]
Fig.5 Drying leaf.

Therefore natural pigments and mordant from our province were investigated, whereby several tests were conducted to obtain a pure extraction of pigment. These included:
Ÿ   Annatto, cabbage (Brassicaoleracea), Carmine cochineal (Genipa), Walnut (nucalis), Avocado;
Ÿ   Pigments used by the Shuar ethnic group: Cumbia, Pitajaya, Guava, Sua.
The tonality of the dye obtained dye from each plant depends on the weather, the soil, and the time of its harvest. These natural pigments are concentrated in the flowers, fruits and leaves, however in colder periods they are concentrated in the bark and wood. [24] Another factor is the soil state as acids and minerals present alter the stability, brightness and strength of the dye. [14] Though the raw materials are extracted through boiling every case varies. Pigment colorings are mostly concentrated in the cellular vacuoles of any number of plants, which when not in a extracted state are associated with other principles such as oils.[16]
In the colouring process the fibers which are going to be stained must be cleaned of impurities. [2]So
Fig.6 Cotton fiber (Gossypiumherbaceum).

that the pigment is better retained as naturally occurring plant elements such as oil prevent dye retention.[17] In the extraction of red cabbage (Brassicaoleraceavar), it is better cut into pieces for easy handling. One needs to boil it for an hour or until the pigment is separates from the vegetables Boiling needs to be gentle so that the water does not evaporate. [7] The resulting mixture is then left to marinate awhile. Adding water whilst boiling is not recommended in order to retain maximum intensity.[18]
The use of mordants is also needed according to the type and weight of the fiber.[19] In the case of banana fiber (raquis), more pigment and mordant is required since the natural characteristic color is darker. During heating, a lemon (Citrus limonumRisso)  mordant is used for raquis. When a mixture of 1000 ml water with 100ml pure lemon is added, one quickly notices how fast the tonality of the color becomes more intense (red). [18] After introducing the fiber, we let all the extract obtained concentrate until it is completely consumed by fire. We have experimented with different types of natural mordant as ash, salt, urine, and walnut bark. To get a better impregnation of color and better brightness,add vinegar to this procedure. [25]
Soon after the fiber is cooled, washed with cold water, and dried on strings.[11] We wish to emphasize that the use of mordants creates a fundamental difference. Salt and vinegar show darker and opaque tonalities, whilst alum provides shinier and stronger tonalities. [23]
Withthese results of the remaining fiber threads were used to make artistic sculptures. [3]
Sculpture and reliefs: Through varied tests it was demonstrated that natural fibers can be applied in different high relief and sculpture techniques [20]. As is the case with mud techniques, the pulp was placed on plaster moulds. [13] Another method to obtain the desired relief was to use of wooden pallets, placing them one over another and gluing them with methyl cellulose (Fig. 11). As with the previous method the fiber was pulverized and mixed with water and glue until a pliable dough could be adhered to the blades.
Another very effective result is to extract the fiber from the raquis plant, wash it, and whilst drying in an Industrial dryer, bath it in Methyl Cellulose [21]. The fiber can molded until the desired volume of the object or work is obtained. [16]
Different artistic techniques were also explored,



Fig.7Red cabbage (Brassicaoleraceavar).

Fig.8 Tinting red cabbage (Brassicaoleraceavar) with natural lemon mordant (Citrus limonumRisso).

Fig.9 See Fig.10. Sculpture made by Liliana Jimenez. Department of Art and Design at Universidad Técnica de Loja.

Fig.11 High relief produced by Josue Mora, Art and Design Department, Universidad Técnica Particular de Loja, sisal pulp in mud.

Fig.12 Sisal sculpture, Sara Jaramillo’s work, of Art and Design Department, Universidad Técnica Particular of Loja.

Fig.13 Artistic photography using abaca paper and Paola Veintimilla’s work, Art and Design Department, Universidad Técnica Particular de Loja.

Fig.14 Banana fiber marbling paper. 

LampsnaturalfiberpaperwithsymbolismofSaraguroethnicityMaría Gabriela Punín work, Art and Design Department, Universidad Técnica Particular de Loja.


such as sculpture, bas reliefs, marbling and crafts, painting techniques on natural fiber paper. In the case of photography, chemical compounds with emulsions from IXX century, sensitivity, resistance, and naturally colored paper were investigated. [5]
To make photographic works on natural fiber paper, the sheets were covered with gelatin (semi-solid) to conglomerate the silver halide grains in the photographic emulsions, as is normal procedure with photographic paper. [4]



COMMON N.  FIBERS
P. to. USE
Cooking Time
COLOR, TEXTURE        FEATURES
NaOH
Banana tree (musaxparadisiacaL)
Pinzote


45, 60 min.

Lisa                    coffee            15%
Yucca
(elephantipesRegel)
Leaf
50 min
Boiling time
Semi smooth            ocher            10%
Cotton
(bombacaceas)
Seed
Boiling time 120 minutes
Rough           white        30%

N of
Practice
Fiber quantity
Firing Time ( from boiling time)
Quantity of
NaOH

Dry Time

Shake Time

Amount of Water
Quantiy  of Tuna
CMC Quantity

Results


PH

1

250 gr

45 min

40 gr

2 days

1min

5000 ml

2000 ml

2000 ml

Less lignin, more flexibility

9

2

250 gr

30 min

35 gr

2 days

0.5 min

5000 ml

2000 ml

2000 ml

Less NaOH, more lignin, less flexibility

12

3

250 gr

60 min

25 gr

2 days

0.8 min

5000 ml

2000 ml

2000 ml
Less lignin, more flexibility, paper whitener

10


Transparency, flexibility and permeability are the factors which determine if the paper is appropriate for the emulsion.[22]The emulsion needs to still change from liquid to solid and to protect the silver grains within.
A low heat dissolution and water bath with a thick distilled water solution (as the composition depends on the unity of H2O molecules) is used. The gelatin solution is put on the back of the natural fiber paper. Whereas the silver halide is placed on the side where the gelatin is not found as it is sensitive to light and reacts to contact with it.
In the marbling process, the natural fiber paper is submerged in a deep container of water, which has floating oil-based inks in it.[23] These inks can be moved with a fine brush to move the suspended ink stains until we the desired design is achieved. The results are then pressed to be used in crafts. [15] Abaca or banana paper is recommended for this process. [8]
Other crafts that work with natural fiber paper, using different short-cycle plants and raw materials that are considered waste as onion peel, stalk, garlic, etc [24].
3. Results
Results obtained from the experimentation and analysis of fibers demonstrating the most variation are detailed below.
Waste from the plant parts was salvaged and recycled into the paper: banana (stalk), palm (leaves), coconut (husk).
A coating glaze use is very useful in the processing and manufacturing of fiber as it reduces the absorption of moisture. This allows the manipulation of different inks and pigments on the paper for artistic purposes such as the techniques of gouache, watercolor, etc.
The use of artificial mordants weaken the fiber. With natural mordants better results were obtained, getting a better color setting.
This project has enabled us to reaffirm that the fact that natural fiber paper is a valuable resource for artwork, as demonstrated in the fields of photography, art-installation, marbling, watercolor, sculpture.
4. Conclusions
Some parts of the plantwhichhave been considered aswaste, such us the banana stalk, palm leaves and the coconut huskhave been salvaged in order to be recycled and used in the production ofnatural fiberpaper.
Ÿ   The use of acoating glaze is very helpfulin theprocessing and manufactureof fiberasit reduces themoisture absorption,this fact allows the manipulationof differentinks andpigments for the application of techniques such asgouache,watercolor,etc. for artistic purposes.
Ÿ   The use ofartificialmordantsweakenthe fiber, better results were obtained withthe use of naturalmordantswhich also lead to a better color fixation.
Ÿ   his project hasenabled us to confirmthat the use ofnaturalfiber paperis a valuableresource forthe artistic work due to the fact that we have appliedit in the fields ofphotography, installations, marbling, watercolor and sculpture.
References
[1]     ALPHA, Betaand Gamma Cellulose in Pulp, TAPPI Test Method T 203 os-74. TAPPI Press, Atlanta.
[2]     A.Solis, Plant Fibers in Ecuador, Casa de la Cultura Ecuatoriana, Quito, Ecuador, 1952.
[3]     BARRAGAN, A. C. The Application of Design of Experiments in the polyester dyeing procedure. Thesis degree in Industrial Engineering. Universidad de las Américas. Puebla, México. 2007.
[4]     B. Peter,Luckmann, Thomas: The Social Construction Theory, Amorrortu editores.
[5]     B. Manuela, Ghost Tour by Shuar territory, Quito, Ecuador, 2007.
[6]     BOERO, A. J. Air Heating System Design and Drying Chamber for Toquilla Staw for Energy Recovery from Traditional Ovens for Cooking Straw. Mechanical Engineering Thesis. Escuela Superior Politécnica del Litoral. Guayaquil, Ecuador. 2008.
[7]     C.A. Agudelo, M.J. Lis, J. Valldeperas, J.A. Navarro. Direct Reuse of Dyeing Baths: Polyester Microfibers and disperse dyes, Boletín INTEXTER (U.P.C.) 2006. Nº. 129.
[9]     C. James, Pulp and Paper, Chemistry and Chemical Technology. México: Limusa, 1990.
[10]   C. Ricardo, Roots of new millenium, Argentina, Grabart – Papel & Estampa, 2005.
[11]   C.Caillavet, Etnias del Norte. Ethnohistory and History of Ecuador, Ediciones ABYA Yala, Quito, Ecuador, 2000.
[12]   Pulp, Paper, Division atipca, Asociación Argentina de fabricantes de celulosa y papel, 2006.
[13]   Consorcio Internacional para el desarrollo Industrial de las Fibras Naturales “CONFIB”.
[14]   Inbar,  Red Internacional del Bambú y Ratán, 2009.
[15]   A.S.Intriago,M.G.Perez,D.L.Villao, Proyect on Utilization of Abaca Fiber in the Development of Handicraft Furniture in Santo Domingo city for using in Guayaquil city. Thesis Degree in International Business Management Engineering. Escuela Superior Politécnica Del Litoral.Guayaquil, Ecuador. 2009.
[16]   Ecuador’s natural fibers, http:/www.sica.gov.ec.
[17]   Racism in Contemporary Ecuador, Ediciones Abya Yala, Quito, Ecuador, 2001.
[18]   NEUMAN Giti Manual for the manufacture of natural fiber paper, Quito- Ecuador
[19]   M. Claudio, Handicrafts in America, Cidap, Cuenca, Ecuador, 2006.
[20]   M.J. Lis, J. Valldeperas, F. Carrillo, J.A. Navarro, Kinetics Analysis and Mathematical Tencel dyeing with direct dyes. Boletín INTEXTER (U.P.C.) 2006. Nº. 130.
[21]   M. Williams, Making your own Napier machié creative ideas for beautiful designs, 1995.
[22]   P.A. Josep, E. Paper, Techniques and traditional processing methods, Ediciones Parramón, 2004.
[23]   R.E. Rhoades, Identity development, Editorial Abya Yala, Quito, Ecuador, 2006.
[24]   Technical Association of the Pulp and Paper Industry, Papeles y Cartones. Numero de Kappa en pulpa. México: TAPPI, 1993.
[25]   Servicio de Información y Censo Agropecuario del Ministerio de Agricultura y Ganadería del Ecuador [online]. Ethnobotany of Natural Fibers in Ecuador <URL:http:/www.sica.gov.ec>







Corresponding author: María Gabriela Punín Burneo, master student. Research field: arts. E-mail: mgpuninx@utpl.edu.ec.

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